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If you enabled User Elevation in Duo for Windows Logon v4.1.0 or later, you'll see the Duo authentication prompt after you enter your password for a credentialed elevation request. The application you were trying to launch runs after you approve the Duo two-factor request. If you chose to remember the device at the Windows desktop login, then you won't need to approve Duo authentication for UAC elevations made by the same logged-in account either until the trusted Duo session ends.