Updated the guide with the results of our CSS3 email client tests. 21 new properties were added, with varying levels of support observed across the popular email clients. Notably, Webkit clients were big winners, including Apple Mail, iPhone Mail and soon, the iPad. At this stage, CSS3 is recommended for decorative purposes in email (such as adding text-shadow), due to poor support for layout and box-model properties.
Discuss this on our blog.