Since there is only one WiFi hardware on the computer its not possible to connect one WiFi hardware to multiple WiFi networks, if you want to that I think you have to map WiFi hardware to guest OS and how host you'll have to use some other hardware (may be Ethernet) but I'm sure that it will work in that way as no VM software allow us to allocate Hardware to Guest except for USB, you can also get USB WiFI and allocate that to VM only.